Sorptive dilation of polysulfone and poly(ethylene terephthalate) films by high‐pressure carbon dioxide
作者:
Yoshinori Kamiya,
Takuji Hirose,
Yasutoshi Naito,
Keishin Mizoguchi,
期刊:
Journal of Polymer Science Part B: Polymer Physics
(WILEY Available online 1988)
卷期:
Volume 26,
issue 1
页码: 159-177
ISSN:0887-6266
年代: 1988
DOI:10.1002/polb.1988.090260109
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractDilation of polysulfone (PSUL) and crystalline poly(ethylene terephthalate) (PET) films accompanying sorption of carbon dioxide is measured by a cathetometer under high pressure up to 50 atm over the temperature range of 35–65°C. Sorptive dilation isotherms of PSUL are concave and convex to the pressure and concentration axes, respectively, and both isotherms exhibit hysteresis. Each dilation isotherm plotted versus pressure and concentration for the CO2‐PET system shows an inflection point, i.e., a glass transition point, at which the isotherm changes from a nonlinear curve to a straight line. Dilation isotherms of PET below the glass transition point are similar to those of the CO2‐PSUL system, whereas the isotherms above the glass transition point are linear and exhibit no hysteresis. Partial molar volumes of CO2in these polymers are determined from data of sorptive dilation. On the basis of the extended dual‐mode sorption model and the current data, primitive equations for gas‐sorptive dilation of glassy polymers ar
点击下载:
PDF
(898KB)
返 回