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Atomic theories of phyllosilicates: Quantum chemistry, statistical mechanics, electrost...
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Atomic theories of phyllosilicates: Quantum chemistry, statistical mechanics, electrostatic theory, and crystal chemistry
作者:
William F. Bleam,
期刊:
Reviews of Geophysics
(WILEY Available online 1993)
卷期:
Volume 31,
issue 1
页码: 51-73
ISSN:8755-1209
年代: 1993
DOI:10.1029/92RG01823
数据来源: WILEY
摘要:
This is a review of quantum chemical, statistical‐mechanical, electrostatic, and crystal chemical studies of phyllosilicates. Atomic‐level studies have examined the structure and bonding within phyllosilicate layers, the effects of cation substitution on bonding and charge distribution, the structure of water, and the distribution of cations in the interlayer, and the bonding between phyllosilicate layers. The major needs for future research are statistical‐mechanical simulations of ion exchange reactions, electron transport in transition‐metal‐containing phyllosilicates, structure and bonding at phyllosilicate edges, and mechanisms of crystal growth and di
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