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Cobalt(II) Complexes With 8-Aminoquinoline Derivatives

 

作者: M. Izquierdo,   J. Casabó,   C. Díaz,   J. Ribas,  

 

期刊: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry  (Taylor Available online 1983)
卷期: Volume 13, issue 7  

页码: 843-854

 

ISSN:0094-5714

 

年代: 1983

 

DOI:10.1080/00945718308059347

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This article describes some complexes of Co(II) with 5,7-dichloro-8-aminoquinoline (dcaq), 5,7-dibromo-8-amino-quinoline (dbaq) and 5,7-diiodo-8-aminoquinoline (diaq). The compounds are of the stoichiometry CoCl2L, CoBr2L2, CoI2L2, Co(NO3)2L2(where L = dcaq or dbaq). Only one complexe has been prepared with diaq, namely CoI2(diaq)2. The elemental analysis are in agree with the formulae, proposed. The i.r. spectra of compounds containing NO3show the presence of ionic and bridging nitrato groups. The electronic spectra and magnetic moments at room temperature are consistent with distorted octahedral geometry around the Co(II) for some of the complexes. We propose polymeric structures with bridging NO3and CI for the compounds Co(NO3)2(ligand)2where (ligand = dcaq, dbaq) and CoCl2(ligand) where (ligand = dcaq, dbaq). Monomeric octahedral structures are proposed for the other compounds.

 

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