Advances and Perspectives in Near-Infrared Spectrophotometry
作者:
JamesK. Drennen,
ElizabethG. Kraemer,
RobertA. Lodder,
期刊:
Critical Reviews in Analytical Chemistry
(Taylor Available online 1991)
卷期:
Volume 22,
issue 6
页码: 443-475
ISSN:1040-8347
年代: 1991
DOI:10.1080/10408349108051642
出版商: Taylor & Francis Group
关键词: chemometrics;pharmaceutics;in-line;on-line;at-line
数据来源: Taylor
摘要:
Near-infrared spectrophotometric analysis is a rapid technique that typically uses the reflectance of a solid sample at several wavelengths to determine the sample's composition. A computerized modeling process is generally used to correct for background and sample-matrix interferences. The modeling process employs a training set of samples to, in effect, “teach” the computer to recognize relationships between minute spectral features and sample composition. The contents of the training-set samples must be determined initially by some other reference method before applying the near-IR technique. The model developed from near-IR spectra and reference values gives the sample composition using a number of linear equations. Each of these equations expresses a particular component concentration as a weighted sum of the signals observed at a number of near-IR wavelengths. Instruments used for near-IR spectrophotometry can be as simple as a filter photometer or a grating monochromator. The broad spectral peaks and highly correlated wavelength vectors generally limit the number of wavelengths used in the model. Little or no sample preparation is required by near-IR methods, and many solid samples can be directly analyzed. Near-IR spectrophotometry has found application in agriculture, industry, biology, medicine, and even satellite remote sensing.
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