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Advances and Perspectives in Near-Infrared Spectrophotometry

 

作者: JamesK. Drennen,   ElizabethG. Kraemer,   RobertA. Lodder,  

 

期刊: Critical Reviews in Analytical Chemistry  (Taylor Available online 1991)
卷期: Volume 22, issue 6  

页码: 443-475

 

ISSN:1040-8347

 

年代: 1991

 

DOI:10.1080/10408349108051642

 

出版商: Taylor & Francis Group

 

关键词: chemometrics;pharmaceutics;in-line;on-line;at-line

 

数据来源: Taylor

 

摘要:

Near-infrared spectrophotometric analysis is a rapid technique that typically uses the reflectance of a solid sample at several wavelengths to determine the sample's composition. A computerized modeling process is generally used to correct for background and sample-matrix interferences. The modeling process employs a training set of samples to, in effect, “teach” the computer to recognize relationships between minute spectral features and sample composition. The contents of the training-set samples must be determined initially by some other reference method before applying the near-IR technique. The model developed from near-IR spectra and reference values gives the sample composition using a number of linear equations. Each of these equations expresses a particular component concentration as a weighted sum of the signals observed at a number of near-IR wavelengths. Instruments used for near-IR spectrophotometry can be as simple as a filter photometer or a grating monochromator. The broad spectral peaks and highly correlated wavelength vectors generally limit the number of wavelengths used in the model. Little or no sample preparation is required by near-IR methods, and many solid samples can be directly analyzed. Near-IR spectrophotometry has found application in agriculture, industry, biology, medicine, and even satellite remote sensing.

 

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