Determination of Possible Olefin Interference in the Analysis of Lead in Gasoline by Atomic Absorption Spectroscopy
作者:
Takao Nishishita,
Seigo Yamazoe,
WilliamR. Mallett,
Masayuki Kashiki,
Shozo Oshima,
期刊:
Analytical Letters
(Taylor Available online 1975)
卷期:
Volume 8,
issue 11
页码: 849-855
ISSN:0003-2719
年代: 1975
DOI:10.1080/00032717508059058
出版商: Taylor & Francis Group
关键词: lead;gasoline;atomic absorption spectroscopy;olefins;iodine
数据来源: Taylor
摘要:
Atomic absorption spectroscopy has been used to determine the concentration of lead in gasoline. The method employs the use of iodine to “level” the variation in response of different lead alkyls. It has been reported that this method is useless when applied to real gasolines, possibly because of the interference of iodine with olefins in the gasoline. The work performed here shows that olefins do not interfere with the lead analysis even when the concentration of olefins is 254 times that of iodine in the test gasoline.
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