Kinetics of Free Radical Copolymerization. VII. Kinetic Analysis of Ethyl Acrylate-Styrene Copolymerization in Inert Solvent
作者:
A. Fehervari,
T. Földes-Berezsnich,
F. Tüdös,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 3
页码: 347-359
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208056505
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The copolymerization kinetics of the ethyl acrylate/styrene/azo-bis-isobutyronitrile/benzene/50°C system was found to deviate from the classical rate equation of copolymerization. The experimental results could not be interpreted by the diffusion theory, the penultimate effect, or the theory of electron donor-acceptor complexes. Our kinetic data were consistently described by the theory of hot radicals, and the 13 parameters characteristic for the copolymerization system were determined from an adequate number of data at different compositions by a nonlinear least-squares method.
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