Cyclopolymerization. II. Electron Spin Resonance Studies of the Free-Radical Reactions of Some Diolefins
作者:
A.L. J. Beckwith,
A.K. Ong,
D.H. Solomon,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1975)
卷期:
Volume 9,
issue 1
页码: 115-124
ISSN:0022-233X
年代: 1975
DOI:10.1080/00222337508068650
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
ESR spectra have been recorded for a number of radicals generated in a flow cell by interaction of diallylmalonic acid, diallyl ether, diallylamine, and related compounds with amino, hydroxyl, and phenyl radicals in aqueous solution. The results indicate that the radicals initially formed by homolytic addition at one of the double bonds in the diolefins rapidly undergo cyclization to afford product radicals containing five-membered rings.
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