Brillouin scattering and hypersonic relaxation in amorphous polymers
作者:
G.D. Patterson,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1977)
卷期:
Volume 13,
issue 4
页码: 647-664
ISSN:0022-2348
年代: 1977
DOI:10.1080/00222347708212214
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Hypersonic relaxation was studied in amorphous polyisobutylene (PIB), atactic polypropylene (PP), atactic poly(vinyl acetate) (PVA), atactic polystyrene (PS), and bisphenol-A polycarbonate (PC) by Brillouin scattering. The hypersonic loss tan δ was determined as a function of temperature. Only a single loss maximum was observed for the polymers studied in this work. The temperatures of maximum loss are 200°C at 4.95 GHz for PIB, 180°C at 4.11 GHz for PP, 200°C at 4.50 GHz for PVA, 240°C at 5.50 GHz for PS, and 280°C at 5.43 GHz for PC. The present results agree very well with the extrapolated secondary glass-rubber transition lines above the temperature where the primary and secondary lines have merged. The loss process is proposed to be local torsional motions of the polymer backbone which lead to structural relaxation of the fluid.
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