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Untersuchungen zur Verseifung aromatischer Sulfochloride

 

作者: H. Beck,   K. Doerffel,  

 

期刊: Journal für Praktische Chemie  (WILEY Available online 1983)
卷期: Volume 325, issue 1  

页码: 36-40

 

ISSN:0021-8383

 

年代: 1983

 

DOI:10.1002/prac.19833250105

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Studies on the Hydrolysis of Aromatic SulfochloridesThe hydrolysis of aromatic sulfochlorides can bei described by a second‐order law. Due to the strength of the base the constants of velocity are between 10−6(H2O) or 103(OH−) 1 mol−1s−1respectively. The reaction of benzensulfochlorides proceeds according to an addition‐elimination mechanism, whereas benzylic sulfochlorides, reacting with a strong base, proceed to an elimination‐addit

 

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