Untersuchungen zur Verseifung aromatischer Sulfochloride
作者:
H. Beck,
K. Doerffel,
期刊:
Journal für Praktische Chemie
(WILEY Available online 1983)
卷期:
Volume 325,
issue 1
页码: 36-40
ISSN:0021-8383
年代: 1983
DOI:10.1002/prac.19833250105
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Studies on the Hydrolysis of Aromatic SulfochloridesThe hydrolysis of aromatic sulfochlorides can bei described by a second‐order law. Due to the strength of the base the constants of velocity are between 10−6(H2O) or 103(OH−) 1 mol−1s−1respectively. The reaction of benzensulfochlorides proceeds according to an addition‐elimination mechanism, whereas benzylic sulfochlorides, reacting with a strong base, proceed to an elimination‐addit
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