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Diblock copolymers and steric stabilization during flow

 

作者: J. Lyngaae-Jørgensen,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1998)
卷期: Volume 37, issue 2  

页码: 239-253

 

ISSN:0022-2348

 

年代: 1998

 

DOI:10.1080/00222349808220469

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A hypothesis (theory) has been formulated for steric stabilization during simple shear flow of discrete domains of one polymer A in a continuous phase B by block copolymer addition. A limiting solution found when the molecular weights of the components are high predicts preformed small drops stabilized by block copolymers at the interfaces are stable below a critical shear stress τcrbut unstable above τcrInterfacial placement in well dispersed blends of PS/PMMA/PS-b-PMMA was deduced by interfacial tension measurement, structure development studies, and viscosityshear rate studies with and without block copolymers. The experimentally determined critical shear stresses show relatively poor reproducibility (SD ± 10%). For measurements at shear stresses larger than the critical values, interesting time effects are observed, whereas scattering signals are constant at shear rates lower than τcrThe hypothesis is not rejected when compared with experimental data from light-scattering measurements during flow.

 

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