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Concentration Dependence of the Activation Energy for the Hole Drift Mobility of 9-Ethylcarbazole-3-carbaldehyde Hydrazones

 

作者: Satoyuki Nomura,   Yasuhiko Shirota,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 315, issue 1  

页码: 217-222

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808044335

 

出版商: Taylor & Francis Group

 

关键词: hole drift mobility;activation energy;concentration dependence;arylaldehyde hydrazone;carbazole moiety

 

数据来源: Taylor

 

摘要:

A new type of concentration dependence,i.e., intersite-distance (ρ) dependence, of the activation energy for the hole drift mobility of the 9-ethylcarbazole-3-carbaldehyde diphenylhydrazone (ECH) and 9-ethylcarbazole-3-carbaldehyde methylphenylhydrazone (ECMH) dispersed in polycarbonate (PC) is reported. The activation energy for charge transport in the ECH or ECMH-doped PC systems gradually decreases with decreasing ρ for large values of ρ, becoming nearly constant for small values of ρ. This behavior contrasts with that for the 4-diphenylaminobenzaldehyde diphenylhydrazone (DPH)-doped PC system. Specific intermolecular interactions between ECH or ECMH molecules having a planar carbazole moiety at relatively high concentrations are suggested to be responsible for this concentration dependence of the activation energy.

 

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