Concentration Dependence of the Activation Energy for the Hole Drift Mobility of 9-Ethylcarbazole-3-carbaldehyde Hydrazones
作者:
Satoyuki Nomura,
Yasuhiko Shirota,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 315,
issue 1
页码: 217-222
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808044335
出版商: Taylor & Francis Group
关键词: hole drift mobility;activation energy;concentration dependence;arylaldehyde hydrazone;carbazole moiety
数据来源: Taylor
摘要:
A new type of concentration dependence,i.e., intersite-distance (ρ) dependence, of the activation energy for the hole drift mobility of the 9-ethylcarbazole-3-carbaldehyde diphenylhydrazone (ECH) and 9-ethylcarbazole-3-carbaldehyde methylphenylhydrazone (ECMH) dispersed in polycarbonate (PC) is reported. The activation energy for charge transport in the ECH or ECMH-doped PC systems gradually decreases with decreasing ρ for large values of ρ, becoming nearly constant for small values of ρ. This behavior contrasts with that for the 4-diphenylaminobenzaldehyde diphenylhydrazone (DPH)-doped PC system. Specific intermolecular interactions between ECH or ECMH molecules having a planar carbazole moiety at relatively high concentrations are suggested to be responsible for this concentration dependence of the activation energy.
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