Chronopotentiometry
作者:
Peter James Lingane,
Dennis G. Peters,
期刊:
C R C Critical Reviews in Analytical Chemistry
(Taylor Available online 1971)
卷期:
Volume 1,
issue 4
页码: 587-634
ISSN:0007-8980
年代: 1971
DOI:10.1080/1040834nu08542742
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
By the termchronopotentiometrywe mean an electrochemical technique in which a controlled current, usually a constant current, is caused to flow between two electrodes; the potential of one electrode is monitored as a function of time with respect to a suitable reference electrode. The solution is usually, but not necessarily, unstirred and contains an excess of a supporting electrolyte so that diffusion is the principal mechanism of mass transport. This technique is distinguished fromconstant-current coulometric analysisandcoulometric titrimetry1in that the current in chronopotentiometry is sufficiently large that the current efficiency for the reduction of the species of interest falls below 100%, usually within a few seconds. It is distinguished fromgalvanostatics, a constant-current technique useful for the determination of heterogeneous electron-transfer rates,2, 3in that the chronopotentiometric potential-time trace spans several hundred millivolts whereas the galvanostatic potential-time trace extends less than ten millivolts from the equilibrium potential.
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