Reaktivität von Koordinationsverbindungen V. Über die Fe2+‐katalysierte Autoxydation von 1‐Hydrazinophtalazin
作者:
D. Walz,
S. Fallab,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1961)
卷期:
Volume 44,
issue 1
页码: 13-19
ISSN:0018-019X
年代: 1961
DOI:10.1002/hlca.19610440103
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
The reaction of the yellow 1‐hydrazinophthalazine‐iron(I1) complexes with O2has been studied. As shown by pH measurements and reductometric titrations the red oxidised complex contains three ligand molecules, two of which have lost one electron. The high kinetic stability suggests dimerisation of the two radicals and thus formation of a 3‐dentate ligand with tetrazane stru
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