Effect of Degradation by Pumping on Normal Stresses in Polyisobutylene Solutions
作者:
Gary K. Patterson,
Harry C. Hershey,
Charles D. Green,
Jacques L. Zakin,
期刊:
Transactions of the Society of Rheology
(AIP Available online 1966)
卷期:
Volume 10,
issue 2
页码: 489-500
ISSN:0148-6055
年代: 1966
DOI:10.1122/1.549033
出版商: The Society of Rheology
数据来源: AIP
摘要:
Normal stress measurements were made on dilute solutions of polyisobutylene in three low‐viscosity solvents at high shear rates with a jet thrust apparatus in which the thrust tube was mounted on the frame of an analytical balance. Thrust measurements could be easily read to 0.01 g and replicate measurements agreed closely with the original ones. Mechanical degradation of polyisobutylene in cyclohexane and toluene caused significant reductions in(P11−P22)wvalues at high shear rates and in the amount of drag reduction in turbulent flow. Molecular weight distribution curves and estimates of viscosity‐average molecular weights of the fresh and degraded solutions in toluene indicate that these effects noted in this solvent are caused by the breakdown of small amounts of high molecular weight polymer, with only a small change in the viscosity‐average molecular weight.
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