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Photochemically induced reaction between perfluoroacetone and ethane

 

作者: Alvin S. Gordon,   William P. Norris,   R. H. Knipe,   Joseph H. Johnson,  

 

期刊: International Journal of Chemical Kinetics  （WILEY Available online 1975）
卷期: Volume 7, issue 1  

页码: 15-22

 

ISSN:0538-8066

 

年代: 1975

 

DOI:10.1002/kin.550070103

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe gas‐phase photolysis of perfluoroacetone in the presence of ethane has been shown to result in the production of significant amounts of 1, 1‐bis(trifluoromethyl)propanol‐1, (CF3)2(C2H5)COH, and 1, 1, 4, 4‐tetrakis(trifluoromethyl)butane‐1, 4‐diol, (CF3)2C(OH)‐CH2CH2C(OH)(CF3)2. A mechanism is presented which accounts for the relative rates of formation of these products at roo

 

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