Bulk specimens (0.4–4 g mass) of the alloy Pd40Ni40P20have been undercooled consistently to the glass state, with no detectable superficial crystallinity, in a molten flux of dehydrated boron oxide. The minimum dimension of the most massive glass specimen, so formed, was 1.0 cm. The absence of crystallinity in the specimens was confirmed by x‐ray diffraction, scanning electron microscopy, and calorimetry.