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FIELD‐ENHANCED CONDUCTIVITY IN TiO2(RUTILE)

 

作者: O. W. Johnson,  

 

期刊: Applied Physics Letters  (AIP Available online 1968)
卷期: Volume 13, issue 10  

页码: 338-339

 

ISSN:0003-6951

 

年代: 1968

 

DOI:10.1063/1.1652460

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Previously published data on the conductivity changes induced in rutile (TiO2) by an applied field are reinterpreted in the light of new information on the behavior of donor impurities in this crystal. It is suggested that the large increase in conductivity which is usually observed is electronic in nature, and is due to an increase in H+interstitial concentration. The H is introduced at the anode, probably by electrolysis of H2O, migrates through the crystal under the influence of the applied field, then is neutralized at the cathode and escapes from the crystal. Enhanced conductivity results when migration of H+near the cathode is inhibited by Ti4+interstitials, thus increasing H+concentration in the bulk. Other possible mechanisms are considered.

 

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