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Electrochemistry of Pu(III) in Molten LiCl-KCl Eutectic

 

作者: L. Martinot,   G. Duyckaerts,  

 

期刊: Analytical Letters  (Taylor Available online 1971)
卷期: Volume 4, issue 1  

页码: 1-11

 

ISSN:0003-2719

 

年代: 1971

 

DOI:10.1080/00032717108058585

 

出版商: Taylor & Francis Group

 

关键词: molten salts;plutonium;electrochemistry;diffusion;activation energy.

 

数据来源: Taylor

 

摘要:

A chronopotentiometric study of the reaction Pu(III) → Pu(IV) + e−in molten LiCl-KCl eutectic is reported. The diffusion coefficient DPu(III)increased from 4.8.10−6to 27.6.10−6cm2sec−1when the temperature was raised from 400 to 650°C.

 

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