Electrochemistry of Pu(III) in Molten LiCl-KCl Eutectic
作者:
L. Martinot,
G. Duyckaerts,
期刊:
Analytical Letters
(Taylor Available online 1971)
卷期:
Volume 4,
issue 1
页码: 1-11
ISSN:0003-2719
年代: 1971
DOI:10.1080/00032717108058585
出版商: Taylor & Francis Group
关键词: molten salts;plutonium;electrochemistry;diffusion;activation energy.
数据来源: Taylor
摘要:
A chronopotentiometric study of the reaction Pu(III) → Pu(IV) + e−in molten LiCl-KCl eutectic is reported. The diffusion coefficient DPu(III)increased from 4.8.10−6to 27.6.10−6cm2sec−1when the temperature was raised from 400 to 650°C.
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