EUROPIUM EXTRACTION INTO D2EHPA: KINETICS OF MASS TRANSFER IN A STIRRED CELL
作者:
Franz KneißI,
Andreas Geist,
Walter Nitsch,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1999)
卷期:
Volume 17,
issue 3
页码: 475-493
ISSN:0736-6299
年代: 1999
DOI:10.1080/07366299908934624
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The kinetics of europium extraction into D2EHPA is studied in a stirred cell. For the range of concentrations investigated (10−6kmol/m−3≤ [Eu3+] ≤ 10−4kmol/m3; 0.01 kmol/m3≤ [H+] ≤ 0.15 kmol/m3; 0.001 kmol/m3≤ [(HX)2] ≤ 0.05 kmol/m3) extraction rate increases linearly with stirring speed, i.e. mass transfer is limited by diffusion. An increase in proton concentration or a decrease of complexant concentration reduces fluxes but does not change the extraction regime. Based on the found equilibrium constant and individual mass transfer coefficients, extraction rates are calculated showing good agreement with experimental data. The influence of concentrations on extraction rate is explained by the gradient between bulk concentration and interfacial concentration as the driving force for mass transfer in an extraction system controlled by diffusion.
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