CHARACTERIZATION OF HEAVY OIL FRACTIONS OBTAINED FROM THERMAL TREATMENT IN PRESENCE OF SULFIDES AND H-DONOR ADDITIVES
作者:
Michel Thomas,
Bernard Fixari,
PierreLe Perchec,
Louis Lena,
Sylvie Bonnamy,
Daniel Decroocq,
Didier Espinat,
期刊:
Fuel Science and Technology International
(Taylor Available online 1991)
卷期:
Volume 9,
issue 3
页码: 337-353
ISSN:0884-3759
年代: 1991
DOI:10.1080/08843759108942269
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Analytical studies have been performed on effluents issued from thermal conversion of Safaniya Vacuum residue (Arab Heavy) in presence of tetralin, thiophenol and methyldisulfide. In contrast to thermal behavior of the heavy oil alone, low coke amount was produced at high conversion level (up to 50%) beside good product qualities as demonstrated from analysis of the remained 500°C+fractions. H-donor diluent and sulfide additives help effectively in lowering the carbon residue values and maintaining the H/C ratios at the highest values compatible with the conversion. Microstructural parameters of the liquid effluents and their asphaltenic parts are obtained1H and13C NMR spectroscopy and average molecular weight determination. Even at high conversion level results allow to assess a rapid dealkylation process at the first stage of the thermal treatments associated with a good control in the evolution of the size of polyaromatic units. Optical Microscopy and X-ray analysis outline the specific effect of tetralin as a. delayed coking additive.
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