SummaryThe superior clinical performance of several dental amalgams which contain high Cu concentrations and little or no γ2 has stimulated the introduction of a number of new amalgam alloys. This investigation sought to study the nature of the phases present in eight commercial systems after trituration. Samples were powdered for X‐ray diffraction phase analysis or were polished for SEM/EDS analysis. These methods were complementary since they permitted positive identification of the phases and their distribution and composition, respectively.The matrix phase of all systems was γ1 (Ag‐Hg). Cu6Sn5was found as the major Sn‐rich amalgamation product. The Cu6Sn5phase forms reaction zones around the Cu‐rich particles with morphological variations from system to system. All amalgams contained the γ (Ag3Sn) phase, but it was microstructurally distinct only in two particle systems. Small amounts of the γ2 (Sn‐Hg) phase were found in three systems. These results suggest that there are important microstructural variations in the new Cu‐rich systems which could eventually result in variations in clini