The Mechanism of Intersystem Crossing for Some Substituted Aromatic Hydrocarbons
作者:
Attilǎ Yildiz,
CharlesN. Reilley,
期刊:
Spectroscopy Letters
(Taylor Available online 1968)
卷期:
Volume 1,
issue 8-9
页码: 335-343
ISSN:0038-7010
年代: 1968
DOI:10.1080/00387016808049986
出版商: Taylor & Francis Group
关键词: Triplet levels;exchange interaction;intersystem crossing
数据来源: Taylor
摘要:
In view of the experimentally observed energy levels, the mechanism of intersystem crossing for 9,10-diphenylanthracene, 9,10-dimethylanthra-cene, and 1,3,6,8-tetraphenylpyrene is discussed and compared with that for parent hydrocarbons. The proposed mechanism explains the drastic changes in the photophysical properties upon phenyl or methyl substitution at the most active centers of anthracene and pyrene rings.
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