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Alkoxides ofo-silyl benzyl alcohols in cleavage reactions: approaches to benzyl and silyl anion equivalents

 

作者: Paul F Hudrlik,   Jose O Arango,   Yousef M Hijji,   Cosmas O Okoro,   Anne M Hudrlik,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 2000）
卷期: Volume 78, issue 11  

页码: 1421-1427

 

ISSN:0008-4042

 

年代: 2000

 

DOI:10.1139/v99-250

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The alkoxides ofo-silyl benzyl alcohols4undergo cleavage reactions under mild conditions allowing transfer of a benzyl or silyl group to an electrophile. Reactions3a8, and3cor4c11illustrate their potential as benzyl and silyl anion equivalents.Key words: silyl migration, benzyl anion equivalent, silyl anion equivalent, &bgr;-silyl ketone, &ggr;-hydroxysilane.

 

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