Molecular Dynamics of Smectic Liquid Crystalline Side-Chain Polymers as Studied by Dielectric Relaxation Spectroscopy
作者:
Kazuo Araki,
Maki Yamaguchi,
Seiji Ujiie,
Kazuyoshi Iimura,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 261,
issue 1
页码: 491-499
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033492
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The dielectric properties of the liquid crystallline polymethacylates with side chain containing a terminal alkyloxy chain have been over wide ranges of frequency and temperature. The temperatures corresponding to the peak of the dielectric loss tangent for PM6BP and PM6BP5 in its temperature dependence agreed well with those phase transition. The activation energies at low temperature agreed with Δ-relaxation which is ε-relaxation by rotation of mesogenic gruop around the backbone chain. The dipole moment have been calculated by using the Frohlich modification of Onsager's equation. The alignment of both materials in the present of an a.c. electric field are also discussed.
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