The alkaline hydrolysis of dimethylformamide has been studied at 40'C in micellar solutions of single surfactant (CTAB. SDS. Brij 35) with the analog thermoanalytical curve method of thermokinetics. A kinetic equation of micellar catalysis under the condition of highter reactant concentration than micellar concentration ([S]>[M]) has been derived from the pseudophase model of micellar catalysis and some relative assumptions, The kinetic parameters. km, k2mand the association constant of reactant with micelle K1, have been calculated in this way. the results indicate that these surfactant micelles exhibit catalytic effect on the reaction. This is attributed to the micropolarity and local concentration effect of micelles.