ISSN 0300-9238 JCFTAR 84(8) 251 9-291 4 (1 988) 2519 2537 2545 2553 2567 2573 258 5 2595 2603 2609 2619 2635 264 1 JOURNAL OF THE CHEMICAL SOCIETY Faraday Transactions I Physical Chemistry in Condensed Phases The first 13 papers of this issue are on the Physical Chemistry of Small Carbohydrates, part of the 8th International Solute-Solute-Solvent Interaction Symposium held at Regensberg University in August 1987. CONTENTS Derivation of Parameters for Conformational Calculations on Carbohydrate Systems, including Bacterial Cell Wall Peptidoglycan A. Marsden, B. Robson and J. S. Thompson Correlation between the Hydrophobic Nature of Monosaccharides and Cholates, .and their Hydrophobic Indices K. Miyajima, K. Machida, T. Taga, H. Komatsu and M. Nakagaki Homotactic and Heterotactic Interactions in Aqueous Solutions containing some Saccharides.Experimental Results and an Empirical Relationship between Saccharide Solvation and Solute-Solute Interactions S. H. Gaffney, E. Haslam, T. H. Lilley and T. R. Ward Excess Enthalpy and Excess Volume in Ternary Aqueous Solutions with Sucrose-Glucose, Sucrose-Glycerol and Glucose-Glycerol at 298.1 K N. Daldrup and H. Schonert Interactions between Cations and Sugars. Part 4.-Free Energy of Interaction of the Calcium Ion with Some Aldopentoses and Aldohexoses in Water at 298.15 K J-P. Morel, C. Lhermet and N. Morel-Desrosiers Interaction of Divalent Cations with Polyuronates A. Cesaro, F. Delben and S. Paoletti Fourier-transform Infrared Vibrational Circular Dichroism of Simple Carbo- hydrates C.M. Tummalapalli, D. M. Back and P. L. Polavarapu A Nuclear Magnetic Resonance Study of Isomeric Pentitols in Aqueous and Non-aqueous Solutions F. Franks, R. L. Kay and J. Dadok Conformaton of Polyols in Water. Molecular-dynamics Simulation of Mannitol and Sorbitol J. R. Grigera Influence of Water on Pure Sorbitol Polymorphism S. Quinquenet, C. Gr abielle-Madelmont, M. Ollivon and M. Serpelloni Thermomechanical Properties of Small-carbohydrate-Water Glasses and ' Rubbers '. Kinetically Metastable Systems at Sub-zero Temperatures H. Levine and L. Slade Structure, Sweetness and Solution Properties of Small Carbohydrate Molecules G. G. Birch and S. Shamil Solution Properties and the Sweet Taste of Small Carbohydrates M. Mathlouthi and A-M. Seuvre 2651 Thermodynamic Studies of Transfer of Some Amino Acids and Peptides from Water to Aqueous Glucose and Sucrose Solutions at 298.15 K R.Bhat, N. Kishore and J. C. Ahluwalia 83 FAR 12667 2677 2683 2697 2703 2723 2735 2755 277 1 2783 2795 2807 282 1 283 1 2843 2855 2875 2885 2895 Effect of Micelle Formation on the Absorption Spectra of a Functionalized Detergent with the Anthraquinone Moiety K. Hoshino, T. Saji, K. Suga and M. Fujihira Synthesis of a Viologen-Tetratitanate lntercalation Compound and its Photochemical Behaviour H. Miyata, Y. Sugahara, K. Kuroda and C. Kato Salt Solutions in Supercritical Water. Some Preliminary Studies on the Influence of Gravity Thermodynamics of Transfer of Glycine, Diglycine, p-Nitroaniline and Benzoic Acid from Water to Aqueous Solutions of Polyhydroxy Compounds J.P. Chatterjee and I. N. Basumallick Transfer Chemical Potentials for Ions, Solubilities of Salts and Kinetics of Reactions involving Inorganic Complex Ions at Ambient Pressure and 298.2 K in Binary Aqueous Mixtures containing Ethanol and Propan-2-01 M. J. Blandamer, B. Briggs, J. Burgess, D. Elvidge, P. Guardado, A. W. Hakin, S. Radulovic and C. D. Hubbard Crystallisation Kinetics of Calcite in the Presence of Magnesium Ions W. A. House, M. R. Howson and A. D. Pethybridge Nuclear Magnetic Resonance Relaxation Study of I- and Na' Solvation Structure in N-Methylformamide (NMF) and Preferential Solvation of these Ions in the Mixture NMF-H,O Multicomponent Ion Exchange in Zeolites. Part 4.-The Exchange of Magnesium Ions in Zeolites X and Y Dynamic Studies of the Photoinduced Metathesis of C,H, and Photoreduction of Mo with CO on Anchored and Impregnated Mo/SiO,Catalysts M.Anpo, M. Kondo, Y. Kubokawa, C. Louis and M. Che Investigation of Structural Changes in the Nickel-Uranium Oxide Catalyst System by Uranium &-Edge and Nickel K-Edge EXAFS and XANES F. J. Berry, A. Murray and A. T. Steel Metal Oxides as Heterogeneous Catalysts for Oxygen Evolution under Photochemical Conditions A. Harriman, I. J. Pickering, J. M. Thomas and P. A. Christensen Kinetics of the Interacton of Acridine Dyes with Nucleic Acids. An Iodine-laser Temperature-jump Investigation B. Marcandalli, G. Stange and J. F. Holz- warth Iridium Oxide Hydrosols as Catalysts for the Decay of Zinc Porphyrin Radical Cations in Water Thermal Decomposition of KIO, and NaIO, in Relation to Solid-state Isotopic Exchange Reactions CO Adsorption on MgO and CaO.Spectroscopic Investigations of Stages .prior to Cyclic Anion Cluster Formation E. Garrone, A. Zecchina and F. S. Stone Successive Addition of Electrons to Sodium Quinizarin-2- and -6-Sulphonate in Aqueous Solution. A Pulse and y-Radiolysis Study T. Mukherjee, E. J. Land, A. J. Swallow, P. M. Guyan and J. M. Bruce Electron Spin Resonance and Electron Nuclear Double Resonance Study of Mixed Crystals of Benzophenone and Diphenylnitroxide A. L. Maniero and M. Brustolon Correlation of the Solvation Properties of Water and Dimethyl Sulphoxide in Metal Nitrate-Water and Metal Nitrate-Dimethyl Sulphoxide Melts with the Molecular Properties of the Constituents of the Melts G. A. Sacchetto and Z. Kodejd Measurements of Tracer Diffusion Coefficients of Sulphate Ions in Aqueous Solutions of Ammonium Sulphate and Sodium Sulphate, and of Water in Aqueous Sodium Sulphate Solutions D. J. Turner C. K. Finter and H. G. Hertz K. R. Franklin and R. P. Townsend A. Harriman, G. S. Nahor, S. Mosseri and P. Neta S. Takriti and G. DuplQtre K. Tanaka2899 Review of Books A. D. Yoffe; G. J. T. Tiddy; R. N. Perutz; J. Klinowski; S. K. Scott; A. Keller; K. Stead; M. J. Blandamer; G. Saville; S. K. Scott; S. M. Richardson; N. V. Richardson; M. R. Mackley; L. V. C. Rees; C. J. Wormald; N. Sheppard; A. R. Jones 83-22899 Review of Books A. D. Yoffe; G. J. T. Tiddy; R. N. Perutz; J. Klinowski; S. K. Scott; A. Keller; K. Stead; M. J. Blandamer; G. Saville; S. K. Scott; S. M. Richardson; N. V. Richardson; M. R. Mackley; L. V. C. Rees; C. J. Wormald; N. Sheppard; A. R. Jones 83-2