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Chemical and Topological Order in the Vicinity of Phase Separation

 

作者: R.N. Singh,  

 

期刊: Physics and Chemistry of Liquids  （Taylor Available online 1997）
卷期: Volume 34, issue 4  

页码: 249-253

 

ISSN:0031-9104

 

年代: 1997

 

DOI:10.1080/00319109708030569

 

出版商: Taylor & Francis Group

 

关键词: Coordination number;segregation

 

数据来源: Taylor

 

摘要:

A statistical thermodynamic model is used to establish a link between the chemical order, topological order and the concentration fluctuations in the nearest neighbour shell of a binary mixture. The topological order related to density fluctuations is found to play the dominant role in the process of phase separation.

 

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