Relationship between Morphology and Deformation Mechanisms of Polyolefins
作者:
K. Sasaguri,
S. Hoshino,
R. S. Stein,
期刊:
Journal of Applied Physics
(AIP Available online 1964)
卷期:
Volume 35,
issue 1
页码: 47-54
ISSN:0021-8979
年代: 1964
DOI:10.1063/1.1713097
出版商: AIP
数据来源: AIP
摘要:
The birefringence of polyolefins undergoes a change from an initial negative value at low elongation to a positive value at higher elongations. The extent of the negative contribution depends upon time after quenching the sample and upon temperature. The changes result from a change in the mode of crystal orientation. A model involving spherulite deformation and reorientation of crystals within the spherulite is proposed. Changes with time and temperature are ascribed to changes in a parameter &ggr; describing the mobility of crystals within the spherulites. The model is also used to account for variation in the dynamic birefringence with straining frequency.
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