Spectral study of mono‐meso‐(hydroxyphenyl)octamethylporphyrins
作者:
Li Ming,
Chen Xiao‐Yu,
Zou Jiang‐Zong,
Xu Zheng,
You Xiao‐Zeng,
期刊:
Chinese Journal of Chemistry
(WILEY Available online 1996)
卷期:
Volume 14,
issue 1
页码: 20-24
ISSN:1001-604X
年代: 1996
DOI:10.1002/cjoc.19960140105
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: Mono‐meso‐(hydroxyphenyl)octamethylporphyrins;spectroscopy
数据来源: WILEY
摘要:
AbstractThe behaviour of porphyrins [mono‐meso‐(2‐hydroxyphenyl)octamethylporphyrin, mono‐meso‐(4‐hydroxyphenyl)octamethylporphyrin and mono‐meso‐(3,4‐dihydroxyphenyl)octamethylporphyrin] in basic solution is examined by UV‐Visible and1H NMR spectroscopy. The unusual nature of the spectra may be explained by the formation of porphomethene moieties in which the porphyrin chromophore is modified by interruption of theπ‐system. The porphyrins in bases are less susceptible to oxidation in contrast withmeso‐tetrakis‐(4
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