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Synthesis of Pantonine

 

作者: Norbertde Kimpe,   Marc Boeykens,   Laszlo Lazar,   Gabor Bernath,  

 

期刊: Natural Product Letters  （Taylor Available online 1994）
卷期: Volume 5, issue 1  

页码: 1-6

 

ISSN:1057-5634

 

年代: 1994

 

DOI:10.1080/10575639408043927

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A convenient synthesis of the naturally occurring α-amino acid pantonine, i.e. 2-amino-4-hydroxy-3,3-dimethylbutyric acid, was developed starting from 3-chloro-2,2-dimethylpropanal. Pantonine itself underwent cyclization into the corresponding γ-lactone by reaction with gaseous hydrogen chloride in methanol.

 

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