Effect of polymer order on the vapor pressures of polypropylene solutions
作者:
CharlesA. Daniels,
SamuelH. Maron,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1970)
卷期:
Volume 4,
issue 2
页码: 227-237
ISSN:0022-2348
年代: 1970
DOI:10.1080/00222347008212501
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The Maron theory of polymer solutions was used to reexamine the data of Brown et al. and Allen et al. [1,2] on the vapor pressures of polypropylene solutions in diisopropyl and diethyl ketones. The results obtained show that the interaction parameters for these systems depend on concentration and temperature, and that these parameters are able to reproduce the observed data so long as the polymers are amorphous. However, in the presence of polymer order, deviations from theory are observed which lead to 31 and 61% crystallinity for the two polypropylene samples used in these studies.
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