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Photograft Copolymerization of Methyl Methacrylate, Acrylonitrile, and Acrylamide on Oxycellulose Using Potassium Persulfate as the Initiator in Limited Aqueous Systems

 

作者: Premamoy Ghosh,   TapasKumar Ghosh,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1982)
卷期: Volume 18, issue 3  

页码: 361-370

 

ISSN:0022-233X

 

年代: 1982

 

DOI:10.1080/00222338208056506

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Graft copolymerization of methyl methacrylate (MMA), acrylonitrile (AN), and acrylamide (AA) on cellulose of low degrees of oxidation (effected through periodate treatment) was studied under photoactivation with visible light in limited aqueous systems. The degree of oxidation of the cellulose sample given in terms of copper number was between 0.25 (for the native cellulose) and 46. Increasing degree of oxidation initially produced higher overall % conversion or rate of polymerization. Overall grafting effects, i.e., % grafting and grafting efficiency, were also generally higher in oxycellulose than in unmodified cellulose. Effects of variations of time of polymerization, initiator content, and monomer content on overall grafting were also studied, and related data for the three monomer systems have been presented and compared. Percent grafting as high as 300–500% and grafting efficiency of the order of 80–95% were easily obtained.

 

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