Composition and Conductivity of Tin Oxide Films Prepared by Pyrohydrolytic Decomposition of Tin(IV) Compounds
作者:
HASUCK KIM,
H. A. LAITINEN,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1975)
卷期:
Volume 58,
issue 1‐2
页码: 23-25
ISSN:0002-7820
年代: 1975
DOI:10.1111/j.1151-2916.1975.tb18974.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
The conductivity of thin poly crystalline Sn oxide films prepared by spraying solutions of Sn(IV) compounds onto glass or quartz substrates was studied. Conductivity was decreased by increasing the temperature or prolonging the time of heating after hydrolysis, by substituting SnBr4for SnCl4, and by substituting O2for N2during spraying. These effects are explained in terms of nonstoichiometry of the sample and the presence of residual halogens in the crystal lattice as detected by ion‐probe analysi
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