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Contributions to the Mechanism of Isobutene Polymerization. I. Theory of Allylic Termination and Kinetic Considerations

 

作者: J.P. Kennedy,   R.G. Squires,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1967）
卷期: Volume 1, issue 5  

页码: 805-829

 

ISSN:0022-233X

 

年代: 1967

 

DOI:10.1080/10601326708053737

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Theories dealing with the problem of termination in ionic polymerizations by hydride transfer coupled with allylic stabilization have been examined and extended. It is postulated that cationic polymerizations in general terminate with the irreversible destruction of growing ions by the following mechanism:

 

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