Origin ofFspots and stress sensitivity in lanthanum lead zirconate titanate
作者:
D. Viehland,
Z. Xu,
D. A. Payne,
期刊:
Journal of Applied Physics
(AIP Available online 1993)
卷期:
Volume 74,
issue 12
页码: 7454-7460
ISSN:0021-8979
年代: 1993
DOI:10.1063/1.354968
出版商: AIP
数据来源: AIP
摘要:
In this study a systematic microstructural characterization of La‐modified lead zirconate titanate was carried out by hot‐ and cold‐stage transmission electron microscopy and selected area electron diffraction. The existence of 1/2[111] superlattice reflections (Fspots) became evident near 300 °C on cooling. The intensity of theFspots was found to increase with decreasing temperature, approaching a near constant intensity below 100 °C. In conjunction with compositional studies, it was proposed that theFspots arise from a doubling of the unit cell associated with a tilting of oxygen octahedra. The presence ofFspots at temperatures approaching the onset of local polarization was then interpreted as the existence of a hierarchy of domain states. This hierarchy was proposed to consist of an average‐cubic macroscopic structure containing rhombohedral micropolar regions on the scale of 50–100 A˚ that contain ferroelastic microtwins on the scale of several tens of angstroms.
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