A theoretical investigation of the temperature dependence of the quadrupole splitting of low spin ferric compounds
作者:
R.M. Golding,
期刊:
Molecular Physics
(Taylor Available online 1967)
卷期:
Volume 12,
issue 1
页码: 13-23
ISSN:0026-8976
年代: 1967
DOI:10.1080/00268976700100021
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A method is indicated whereby the quadrupole splitting arising from the d-electrons and the contribution from the crystalline matrix can be determined from the experimental Mössbauer spectra. The general temperature dependence of the quadrupole splitting of the low spin ferric compounds is first calculated from the experimentalg-tensor and then for the case when the iron atom is in a strong crystal field of tetragonal symmetry. Covalency effects are also considered. The parametere2Q'r-3> is determined as 8·9 mm/sec which not only suggests screening effects in these complexes but enables an estimate of the degree of bonding of the iron with the ligands.
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