The structural identification of a secondary dye produced from the reaction between sunset yellow and sodium metabisulphite
作者:
Andrew Damant,
Stewart Reynolds,
Robert Macrae,
期刊:
Food Additives & Contaminants
(Taylor Available online 1989)
卷期:
Volume 6,
issue 3
页码: 273-282
ISSN:0265-203X
年代: 1989
DOI:10.1080/02652038909373783
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The stability of sunset yellow FCF (El 10) was investigated in a model soft drinks system, with and without the addition of sodium metabisulphite. The rate of dye degradation was monitored by spectrophotometry and HPLC. In samples containing both sunset yellow and sodium metabisulphite, the formation of a lemon‐yellow‐coloured compound was clearly demonstrated. Isolation and subsequent analysis by NMR and FAB‐MS showed the structure of the compound to be that resulting from sulphonation at carbon 4 of the sunset yellow molecule. Examination of a stored commercial soft drinks sample indicated the presence of the same lemon‐yellow compound.
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