Oxidation of Methyl tert-Butyl Ether (MTBE) and Ethyl tert-Butyl Ether (ETBE) by Ozone and Combined Ozone/Hydrogen Peroxide
作者:
N. Karpel Vel Leitner,
A.-L. Papailhou,
J.-P. Croué,
J. Peyrot,
M. Doré,
期刊:
Ozone: Science & Engineering
(Taylor Available online 1994)
卷期:
Volume 16,
issue 1
页码: 41-54
ISSN:0191-9512
年代: 1994
DOI:10.1080/01919519408552379
出版商: Taylor & Francis Group
关键词: Ozone;Methyl tert-Butyl Ether;Ethyl tert-Butyl Ether;Ozonation Byproducts;Kinetics;Stripping;tert-Butyl Formate;tert-Butyl Acetate;tert-Butyl Alcohol;Ozone/Hydrogen Peroxide
数据来源: Taylor
摘要:
The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O3/H2O2. Batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH°-radical with MTBE and ETBE [kOH°/ETBE/kOH°/MTBE= 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE and ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds.
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