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Polymerization of styrene in soap solutions

 

作者: V. J. Frilette,   W. P. Hohenstein,  

 

期刊: Journal of Polymer Science  (WILEY Available online 1948)
卷期: Volume 3, issue 1  

页码: 22-31

 

ISSN:0022-3832

 

年代: 1948

 

DOI:10.1002/pol.1948.120030104

 

出版商: Interscience Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractA turbidimetric method has been developed for determining the styrene content in water and soap solution. The solubility of styrene in distilled water was 0.022% while in 2.0% potassium oleate solution it was 0.65 to 0.88%. The course of the polymerization of a saturated solution of styrene in 2% potassium oleate was followed by a colorimetric analysis based on reaction with dilute potassium permanganate. The rate of polymerization decreased rapidly after 50% conversion. The activation energy was estimated to be 17,000 kcal., somewhat less than in solution. The molecular weight of the polymer produced was 200,000. Occasional erratic results were ascribed to possible influence of various amounts of air sealed in the polymerization mixtures.

 

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