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THE ANALYSIS OF METALLOPORPHYRINS IN PETROLEUM USING TANDEM MASS SPECTROMETRY

 

作者: JenniferS. Brodbelt,   R. Graham Cooks,   KarlV. Wood,   ThomasJ. Jackson,  

 

期刊: Fuel Science and Technology International  （Taylor Available online 1986）
卷期: Volume 4, issue 6  

页码: 683-698

 

ISSN:0884-3759

 

年代: 1986

 

DOI:10.1080/08843758608915836

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Vanadyl deoxophy lloerythroetioporphyrins (DPEP) and vanadyl etioporphyrins (ETIO) have been identified in Gato Ridge and Boscan petroleum samples using a combination of isobutane chemical ionization and tandem mass spectrometry. In addition, particular porphyrins such as the C30vanadyl DPEP and ETIO species were identified in a crude oil containing approximately 500 ppm total porphyrins, with only minimal sample clean-up.

 

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