Theory of far infrared spectroscopy for ferroelectric size effects
作者:
Khian-Hooi Chew,
Junaidah Osman,
R.L. Stamps,
D.R. Tilley,
J.F. Webb,
期刊:
Integrated Ferroelectrics
(Taylor Available online 1999)
卷期:
Volume 23,
issue 1-4
页码: 161-186
ISSN:1058-4587
年代: 1999
DOI:10.1080/10584589908210147
出版商: Taylor & Francis Group
关键词: Ferroelectric surface;far infrared;reflection spectroscopy
数据来源: Taylor
摘要:
We propose that far-infrared reflection and transmission measurements would be a sensitive probe of possible variations in the polarizationPof a ferroelectric near a surface. We present a general formulation based on the Landau-Devonshire model, including both linear and nonlinear processes. Surface effects are described by parametersD, giving the free-energy cost of spatial variations inP, and δ, governing the boundary condition onP. Detailed calculations for linear reflection in normal incidence from a semi-infinite medium are presented. If δ−1= 0 the calculations are analytic and the results for this case serve as a check on the numerical calculations that are applied for general δ. Altogether, the results suggest that the effects ofDand δ should be distinct and measurable.
点击下载:
PDF (1751KB)
返 回