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Theory of far infrared spectroscopy for ferroelectric size effects

 

作者: Khian-Hooi Chew,   Junaidah Osman,   R.L. Stamps,   D.R. Tilley,   J.F. Webb,  

 

期刊: Integrated Ferroelectrics  (Taylor Available online 1999)
卷期: Volume 23, issue 1-4  

页码: 161-186

 

ISSN:1058-4587

 

年代: 1999

 

DOI:10.1080/10584589908210147

 

出版商: Taylor & Francis Group

 

关键词: Ferroelectric surface;far infrared;reflection spectroscopy

 

数据来源: Taylor

 

摘要:

We propose that far-infrared reflection and transmission measurements would be a sensitive probe of possible variations in the polarizationPof a ferroelectric near a surface. We present a general formulation based on the Landau-Devonshire model, including both linear and nonlinear processes. Surface effects are described by parametersD, giving the free-energy cost of spatial variations inP, and δ, governing the boundary condition onP. Detailed calculations for linear reflection in normal incidence from a semi-infinite medium are presented. If δ−1= 0 the calculations are analytic and the results for this case serve as a check on the numerical calculations that are applied for general δ. Altogether, the results suggest that the effects ofDand δ should be distinct and measurable.

 

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