Speciation of Charged Complexes by Donnan Dialysis
作者:
JamesA. Cox,
Samar Al-shakshir,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 9
页码: 1757-1769
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808066526
出版商: Taylor & Francis Group
关键词: Lability;ion-exchange;ethylenediamine;triethylenetetramine;o-phenanthroline;copper;iron;nickel
数据来源: Taylor
摘要:
The assignment of metal complexes to various regimes on the basis of their dissociation kinetics is one type of metal speciation study. The most common scheme, which involves column ion-exchange as a means of separating free metal ions and metals in the form of highly labile complexes from other forms of metals in the sample, is demonstrated to categorize incorrectly stable, charged complexes such as iron(II) and nickel(II) o-phenanthroline as labile. Donnan dialysis is an alternative ion-exchange method for metal speciation studies. Data are provided which demonstrate that the above complexes are correctly assigned by the Donnan dialysis method. The relative labilities of ethylenediamine and triethylenetetramine complexes of iron (II) and nickel (II) are also correctly determined by Donnan dialysis.
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