Mechanistic Pathways in the Catalysis of Olefin Hydrocarboxylation by Rhodium, Iridium, and Cobalt Complexes
作者:
Denis Forster,
Arnold Hershman,
DonaldE. Morris,
期刊:
Catalysis Reviews
(Taylor Available online 1981)
卷期:
Volume 23,
issue 1-2
页码: 89-105
ISSN:0161-4940
年代: 1981
DOI:10.1080/03602458108068070
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Carboxylic acids can be synthesized by reacting olefins with carbon monoxide and water in the presence of a variety of transition transition metal catalysts:(1) Metals which have been employed as catalysts for this reaction include nickel, as first reported [1] by Reppe for the synthesis of acrylic and propionic acids from acetylene and ethylene, cobalt, iron, rhodium, ruthenium, palladium, and platinum [2]. The earlier studies of this reaction employed nickel, cobalt, and iron catalysts and required rather severe operating conditions, viz., 200-300 atm and 200-300°C. More recently the use of rhodium [3], iridium [4], platinum [5], palladium [6], and pyridine-promoted cobalt [7] catalysts has been reported. These latter systems all function at relatively mild reaction conditions (see Table 1).
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