Fundamentals of Hydrogels and Gelation
作者:
Simon B. Ross‐Murphy,
Henry McEvoy,
期刊:
British Polymer Journal
(WILEY Available online 1986)
卷期:
Volume 18,
issue 1
页码: 2-7
ISSN:0007-1641
年代: 1986
DOI:10.1002/pi.4980180103
出版商: John Wiley&Sons, Ltd
关键词: hydrogel;biopolymer;shear modulus;mechanical spectroscopy;percolation model;swelling
数据来源: WILEY
摘要:
AbstractA discussion of the properties of that class of materials known as ‘hydrogels’ must make particular reference to (i) a working definition of what is meant by a ‘gel’, (ii) the manner in which this relates to the underlying macromolecular structure, and (iii) how these properties are affected by the presence of water within the macromolecular network. The first point is answered by providing an operational definition of a gel, which depends on the mechanical response of the material to oscillatory shear. This type of behaviour is shown to be quantitatively related to the degree of connectivity of the network. The chemical aspects of the problem address the relationship between this and the degree of reaction achieved by those chemical or physical features responsible for crosslinking. Finally, the swelling properties of such materials are discussed, and how these are complicated by the non‐ideal thermodynamic properties of the solv
点击下载:
PDF
(600KB)
返 回