New Analytical Applications for Sodium Diethyldithiocarbamate
作者:
Kh.Z. Brainina,
T.A. Krapivkina,
期刊:
Analytical Letters
(Taylor Available online 1969)
卷期:
Volume 2,
issue 5
页码: 269-281
ISSN:0003-2719
年代: 1969
DOI:10.1080/00032716908051299
出版商: Taylor & Francis Group
关键词: film polarography;graphite electrode;sodium diethyldithiocarbamate;cobalt
数据来源: Taylor
摘要:
The electrochemical behavior of sodium diethyldithiocarbamate has been studied. A method has been developed to determine trace amounts of the reagent by preparatory electrolysis at a suitable potential which causes the sparingly soluble electrochemical product to precipitate on a small graphite electrode. The inverse polarogram gives a current which can be evaluated quantitatively, produced by the re-dissolving of the film on the electrode. Sodium diethyldithiocarbamate can also be used for electrochemically concentrating cobalt in the form of a sparingly soluble compound of Co(III) by measuring the current required to reduce (re-dissolve) the compound. The electrochemical oxidation reaction of sodium diethyldithiocarbamate to give insoluble films could be used for indirect determination of the metal ions which interact with the reagent.
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