Liquid Anion Exchange Studies and Separation of Mercury
作者:
MissM.R. Shivade,
V.M. Shinde,
期刊:
Analytical Letters
(Taylor Available online 1981)
卷期:
Volume 14,
issue 3
页码: 155-161
ISSN:0003-2719
年代: 1981
DOI:10.1080/00032718108081391
出版商: Taylor & Francis Group
关键词: Mercury;aliquat 336 S;extraction
数据来源: Taylor
摘要:
A new method is developed for the extractive separation of mercury from associated elements. Mercury is quantitatively extracted from 0.5 M acetic acid solution by aliquat 336 S, which acts as a liquid anion exchanger. The metal ion from the organic phase is stripped with sodium hydroxide solution and determined in the aqueous phase complexometrically. The extracted species is [2(R4N+), Hg(OAc)4−2]. A working procedure for the selective separation of mercury from zinc, cadmium, nickel, cobalt, copper, bismuth and manganese is described.
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