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Dry deposition modeling of nitrate and sulfate by using particle size distribution data

 

作者: S. J. Chen,   C. C. Lin,   S. C. Chiu,  

 

期刊: Journal of Environmental Science and Health, Part A  (Taylor Available online 1998)
卷期: Volume 33, issue 2  

页码: 307-334

 

ISSN:1093-4529

 

年代: 1998

 

DOI:10.1080/10934529809376733

 

出版商: Taylor & Francis Group

 

关键词: Dry deposition;modeling;nitrate;sulfate;particle size distribution

 

数据来源: Taylor

 

摘要:

Dry deposition and air sampling: were undertaken simultaneously in the ambient air of Ping Tung area by using several dry deposition plates, two MOUDIs (Micro‐orifice Uniform Deposit lmpactors) and one NRI (Noll Rotary Impactor) from December 1995 to May 1996 in Southern Taiwan. The NRI and MOUDI were used to collect ambient coarse and fine particulate, respectively. Dry deposition plate was applied to collect particle deposition flux. An ion chromatography (Dionex 2000i/SP) equipped with 4 mm AG4A‐SC and AS4A‐SC column was employed to analyze the anion species (NO, and SO42). The eluent solution is 1.8 mM sodium carbonate/ 1.7mM sodium bicarbonate. The calculated dry deposition flux for each particle size range was obtained by using measured mass‐size distribution data between 0.18 and 100 μm diameter and a dry deposition model. The mean modeled/measured (Md/ Ma) ratio of dry deposition flux varied between 1.11 and 1.28, between 1.28 and 1.42 and between 0.88 and 0.97 for nitrate, sulfate and total particle mass, respectively. The results indicated that nitrate and sulfate were slightly overestimated by a dry deposition model, while total particle mass was slightly underestimated by this model. In general, by using the particle size distribution data, this dry deposition model can provide a good predication for the dry deposition flux of nitrate, sulfate and total particle mass. More than 87.5 % of nitrate and more than 92.9%of sulfate dry deposition flux are contributed by particle diameters larger than 10 μm. This is due to the fact that particle size larger than 10 μm have higher dry deposition velocities (>4.65 cm/sec) and control the majority of the dry deposition flux.

 

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