Dependence of Capacitance of Metal-Molten Salt Interface on Local Density Profiles Near Electrode
作者:
P. Ballone,
G. Pastore,
M.P. Tosi,
K.R. Painter,
P.J. Grout,
N.H. March,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1984)
卷期:
Volume 13,
issue 4
页码: 269-277
ISSN:0031-9104
年代: 1984
DOI:10.1080/00319108408080785
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The mean spherical approximation applied to a metal-molten salt interface is generalized to take further account of the local density profiles near the electrode. The temperature dependence of the differential capacitance is shown to arise, in large measure from such local structure. However, the hard wall assumption for the electrode is retained and this must be kept in mind in comparing our model results with experiment.
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