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A shape model for the twisting power of chiral solutes in nematics

 

作者: A. Ferrarini,   G.J. Moro,   P.L. Nordio,  

 

期刊: Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 19, issue 3  

页码: 397-399

 

ISSN:0267-8292

 

年代: 1995

 

DOI:10.1080/02678299508031997

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The twisting power of chiral probes in nematics is interpreted in terms of a shape model, in which the surface elements of the solute molecules tend to align with the local director. The theoretical treatment is based on a previous approach, suitable for relating order parameters in nematics to molecular shape, and leads to the definition of a molecular pseudo-tensor whose orientational average determines the pitch and handedness of the helical macrostructures. Results of numerical calculations performed for distorted biphenyl and binaphthyl molecules are in agreement with the experimental results.

 

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