首页   按字顺浏览 期刊浏览 卷期浏览 Solubility of Thianthrene in Organic Nonelectrolyte Solvents: Comparison of Observed Ve...
Solubility of Thianthrene in Organic Nonelectrolyte Solvents: Comparison of Observed Versus Predicted Values Based Upon Mobile Order Theory

 

作者: KristinA. Fletcher,   MaryE. R. McHale,   JoyceR. Powell,   KarenS. Coym,   WilliamE. Acree,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1997)
卷期: Volume 34, issue 1  

页码: 41-49

 

ISSN:0031-9104

 

年代: 1997

 

DOI:10.1080/00319109708035912

 

出版商: Taylor & Francis Group

 

关键词: Thianthrene solubilities;organic;nonelectrolyte solvents;solubility predictions

 

数据来源: Taylor

 

摘要:

Experimental solubilities are reported at 25.0°C for thianthrene dissolved in twenty-one different organic nonelectrolyte solvents containing ether-, hydroxy-, andt-butyl-functional groups. Results of these measurements combined, with our previously published thianthrene solubility data inn-hexane,n-heptane,n-octanc, cyclohexane, methylcyc-lohexane, 2, 2, 4-trimethylpentane and cyclooctane, are used to test the applications and limitations of expressions derived from Mobile Order theory. For the 20 solvents for which predictions could be made computations show that Mobile Order theory does provide fairly reasonable (although by no means perfect) estimates of the saturation mole fraction solubilities. Average absolute deviation between predicted and observed values iscirca58%. In comparison, the average absolute deviation increases significantly to 1,940% when ideal solution behavior is assumed.

 

点击下载:  PDF (393KB)



返 回